Co3+-O-V4+ cluster in CoVOx nanorods for efficient and stable electrochemical oxygen evolution
نویسندگان
چکیده
The development of cost-efficient and long-term stable catalysts for the oxygen evolution reaction (OER) is crucial to produce clean sustainable H2 fuels from water. Here we demonstrate a cobalt vanadium oxide (CoVOx-300) working as such an efficient durable electrocatalyst. Such active catalyst beneficial balanced Co3+-O-V4+ species, which show high surface Co3+ contents with matched V4+ generated by rapid heat treatment. CoVOx-300 highest Co3+/Co2+ ratio 1.4 corresponding V4+/ V5+ 1.7 exhibits remarkable OER activity overpotential 330 mV at current density 10 mA cm−2 (η10), shallow Tafel slope only 46 dec-1 100 0.38 V vs RHE, 20 times higher than CoOx-300 1000 VOx-300. also shows excellent stability h in alkaline media 40 % reduced activation energy counterpart, CoOx-300. (η10) nearly 70 80 lower CoVOx catalysts, respectively commercial benchmark RuO2. Thus, this study first time demonstrates that species play role improving electrocatalytic properties water oxidation approaches allow rational design synthesis other transition metal oxides toward activity.
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ژورنال
عنوان ژورنال: Applied Catalysis B-environmental
سال: 2021
ISSN: ['1873-3883', '0926-3373']
DOI: https://doi.org/10.1016/j.apcatb.2020.119571